Petroleum, Fuel, Lubricant, Biodiesel & Bioethanol Testing in Pakistan

CWTC provides analytical and laboratory solutions for refineries, lubricant manufacturers, petroleum marketing companies, fuel terminals, oil & gas laboratories, inspection companies, biodiesel and bioethanol producers, renewable-fuel plants, government testing institutes and research facilities across Pakistan.

The portfolio covers ASTM-based petroleum and renewable-fuel testing including TAN and TBN, Karl Fischer moisture, mercaptan sulfur, bromine number and bromine index, crude-oil salt, ion chromatography and Combustion IC, biodiesel / FAME quality control, fuel-ethanol / bioethanol testing, fermentation and process monitoring, inline ethanol concentration, aviation-fuel testing, kinematic-viscosity temperature control and supporting petroleum laboratory equipment.

Petroleum Testing by Application

Select the laboratory or operating environment. Each area has different ASTM requirements, sample matrices and analytical priorities.

Petroleum refinery and petrochemical process analysis
Refineries & Petrochemicals

Refineries & Petrochemicals

Crude desalting, corrosion-related chemistry, mercaptans and sulfur species, refinery streams, process water and online process monitoring.

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Lubricating oil and used oil laboratory testing
Lubricants & Used Oils

Lubricants & Used Oils

TAN, TBN, moisture, additive condition, oxidation-related testing, viscosity workflows and routine lubricant quality control.

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Gasoline diesel and fuel quality testing
Gasoline, Diesel & Fuel Distribution

Gasoline, Diesel & Fuel Distribution

Finished-fuel quality control for terminals, depots and petroleum companies, including acidity, mercaptans, bromine methods, moisture and rapid spectroscopic screening.

Explore fuel methods
Biodiesel bioethanol biofuel ASTM testing with Metrohm BUCHI and ATAGO
Biodiesel, Bioethanol & Renewable Fuels

Biodiesel, Bioethanol & Renewable Fuels

B100 biodiesel, FAME blends, fuel ethanol and renewable-fuel production: acid number, water, glycerin, oxidation stability, acidity, pHe, chloride, sulfate, fermentation QC and inline ethanol concentration.

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Aviation marine and specialty fuel analysis
Aviation, Marine & Specialty Fuels

Aviation, Marine & Specialty Fuels

Jet-fuel acidity, fuel-system icing inhibitor, moisture and other quality parameters for aviation, marine and specialist petroleum products.

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Crude oil exploration production and refinery feed testing
Crude Oil / E&P

Crude Oil / E&P

Water, salt, mercaptans, hydrogen sulfide, crude-oil quality and produced-water chemistry from upstream operations through refinery feed control.

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Independent petroleum fuel inspection and government testing laboratory
Independent Testing / Government / Inspection Labs

Independent & Regulatory Laboratories

Reference-method and contract testing for inspection companies, government laboratories, fuel and emissions laboratories, universities and independent analytical facilities.

Browse ASTM coverage

ASTM & Standard Petroleum / Biofuel Testing Methods

Search by ASTM method, parameter or analytical technique. The table connects common petroleum, fuel, lubricant, biodiesel and bioethanol standards with the relevant analytical platform supplied by CWTC.

ASTM applicability depends on the exact sample matrix, instrument configuration and current edition of the standard. CWTC can help match the required method to the appropriate instrument, sensor, accessory and automation level.
Test / ParameterASTM / StandardTechniqueCWTC Solution
Total Acid Number (TAN)ASTM D664Potentiometric titrationMetrohm automated titration
Acid / Base Number by Color IndicatorASTM D974Photometric titrationMetrohm titrator + Optrode
Acid Number in Crude / Petroleum ProductsASTM D8045Thermometric titrationMetrohm thermometric titration
Total Base Number (TBN)ASTM D2896Potentiometric titrationMetrohm automated titration
Base Number in Used OilsASTM D4739Potentiometric titrationMetrohm automated titration
Mercaptan SulfurASTM D3227Potentiometric titrationMetrohm laboratory / process titration
Hydrogen Sulfide in LPGASTM D2420Potentiometric titrationMetrohm titration
Bromine NumberASTM D1159Electrochemical / potentiometric titrationMetrohm titration
Bromine IndexASTM D2710 / D5776Potentiometric / coulometric titrationMetrohm titration
Acidity in Aviation Turbine FuelASTM D3242Photometric titrationMetrohm titrator + Optrode
Water in Petroleum Products, Lubricants & AdditivesASTM D6304Coulometric Karl FischerMetrohm Coulometer / KF Oven
Biodiesel / FAME – Acid NumberASTM D664Potentiometric titrationMetrohm automated titration
Biodiesel / FAME – Water ContentASTM D6304Coulometric Karl Fischer titrationMetrohm Coulometer / KF
Biodiesel & Biodiesel Blends – Free & Total GlycerinASTM D7591Ion chromatographyMetrohm IC
Biodiesel / FAME – Oxidation StabilityASTM D6751 specification; EN 14112 / EN 15751 / EN 16568Accelerated oxidation stability measurementMetrohm Biodiesel Rancimat
Renewable-Diesel Feedstock – Organic ChlorineASTM D7359 / UOP 991Combustion Ion ChromatographyMetrohm Combustion IC
Fuel Ethanol / Bioethanol – Water ContentASTM D7923 / ASTM E1064Karl Fischer titrationMetrohm KF Coulometer / KF Titrator
Fuel Ethanol / Bioethanol – AcidityASTM D7795Potentiometric / photometric titrationMetrohm titration
Fuel Ethanol / Bioethanol – pHeASTM D6423Electrochemical pHe measurementMetrohm EtOH-Trode / pH measurement
Fuel Ethanol / Bioethanol – Chloride & SulfateASTM D7319Ion chromatographyMetrohm IC
Fuel Ethanol / Bioethanol – Existing / Total SulfateASTM D7318 / D7328Titration / ion chromatographyMetrohm titration / IC
Biodiesel / FAME – Iodine NumberEN 14111Potentiometric titrationMetrohm titration
Water in Crude OilASTM D4928Coulometric Karl FischerMetrohm Karl Fischer
Halogens & Sulfur in LPGASTM D7994Combustion Ion ChromatographyMetrohm Combustion IC + LPG module
Organic Chloride in Naphtha FractionASTM D8150Combustion Ion ChromatographyMetrohm Combustion IC
Salt in Crude OilASTM D3230Conductivity / online process analysisMetrohm 2060 TI Ex Proof Process Analyzer
Salt in Crude Oil – Potentiometric MethodASTM D6470Potentiometric measurementMetrohm electrochemical analysis
Total Nitrogen in Lubricating Oils & Fuel OilsASTM D3228Modified Kjeldahl methodBÜCHI Kjeldahl system
Kinematic ViscosityASTM D445Capillary viscometry at controlled temperatureJULABO DD-31A Visco Bath
Refractive Index of Hydrocarbon LiquidsASTM D1218RefractometryATAGO Abbe Refractometer
Refractive Index of Viscous MaterialsASTM D1747RefractometryATAGO Abbe Refractometer
Fuel System Icing Inhibitor in Aviation FuelASTM D5006RefractometryATAGO RX / Abbe refractometry
RON / MON Rapid ScreeningReference values: ASTM D2699 / D2700NIR prediction calibrated against reference resultsMetrohm NIR spectroscopy

Core Petroleum Testing Technologies

Dedicated analytical platforms for the ASTM and process-control requirements most frequently encountered in refinery, lubricant, fuel and oil & gas laboratories.

Metrohm titrator for petroleum TAN TBN ASTM testing
Metrohm

Automated Titration for Petroleum & Lubricants

Potentiometric, photometric and thermometric titration cover a large part of classical petroleum wet chemistry. Systems range from routine Eco Titrator configurations to modular OMNIS platforms for higher throughput and automation.

ASTM D664 – Total Acid Number
ASTM D2896 / D4739 – Total Base Number
ASTM D3227 – Mercaptan sulfur
ASTM D1159 – Bromine number
ASTM D2710 / D5776 – Bromine index
ASTM D3242 – Aviation-fuel acidity
ASTM D974 – Photometric acid/base number
ASTM D8045 – Thermometric acid number
ASTM D7795 – Acidity in fuel ethanol / bioethanol
ASTM D664 / EN 14104 – Acid number / acid value in biodiesel
EN 14111 – Iodine number in FAME
Metrohm Karl Fischer titrator for petroleum moisture ASTM D6304
Metrohm

Karl Fischer Moisture Analysis

Volumetric and coulometric Karl Fischer systems provide water determination from routine moisture levels down to trace concentrations. For petroleum products, coulometric KF and oven techniques are especially important where matrix effects or very low water levels are involved.

ASTM D6304 – Petroleum products, lubricants and additives
ASTM D4928 – Water in crude oils
ASTM D7923 – Water in ethanol / hydrocarbon blends
ASTM D6304 – Water in biodiesel and fuel matrices
Direct coulometric KF for low-level moisture
KF oven option for difficult or interfering matrices
Volumetric KF for higher water contents
Automation available for routine sample series
Metrohm combustion ion chromatography for petroleum halogen sulfur analysis
Metrohm

Ion Chromatography & Combustion IC

Ion chromatography supports refinery and petroleum-water chemistry, while Combustion IC extends ion analysis to combustible organic matrices. The combination is particularly valuable for halogen and sulfur analysis in fuels and petrochemical samples.

ASTM D7994 – Fluorine, chlorine and sulfur in LPG
ASTM D8150 – Organic chloride in crude-oil naphtha fraction
ASTM D7319 – Chloride & sulfate in fuel ethanol / bioethanol
ASTM D7591 – Free & total glycerin in biodiesel / blends by IC
ASTM D7359 / UOP 991 – Organic chlorine in renewable-diesel feedstock
Halogens and sulfur in combustible organic matrices
Anions and cations in refinery / process waters
Automated sample preparation and matrix handling
930 / 940 IC platforms and Combustion IC configurations
Metrohm 2060 process analyzer for refinery petrochemical online analysis
Metrohm Process Analytics

Online Process Analyzers for Refineries & Petrochemicals

Metrohm process analyzers move critical chemical measurements from periodic laboratory sampling to continuous or automated online monitoring. The 2060 platform can combine wet chemistry, ion chromatography, NIR, Raman and other techniques according to the process requirement.

ASTM D3230 – Online salt monitoring in crude oil
ASTM D3227 / UOP 163 – Mercaptans and H₂S
Titration, KF, photometry, pH, conductivity and ISE options
2060 IC for online ionic species in process streams
NIR / Raman options for continuous composition monitoring
Explosion-proof configurations for hazardous refinery areas
JULABO DD-31A viscosity bath for petroleum kinematic viscosity testing
JULABO

Kinematic Viscosity & Petroleum Temperature Control

JULABO temperature-control equipment supports both direct petroleum test methods and the external heating/cooling requirements of laboratory analyzers, reactors and specialist petroleum-testing assemblies.

DD-31A Visco Bath for ASTM D445 capillary viscosity workflows
High temperature stability for viscometers and density meters
Heating and refrigerated circulators for external temperature control
Counter-cooling for petroleum test equipment
PRESTO systems for jacketed / high-pressure reactors
Temperature control for R&D and petrochemical process development
ATAGO Abbe refractometer for petroleum ASTM refractive index testing
ATAGO

Petroleum Refractometry & Inline Ethanol Concentration

ATAGO Abbe and digital refractometers cover refractive-index measurements used in hydrocarbon, viscous-material and aviation-fuel applications. Dedicated CM-800α and explosion-proof CM-ISα Ethanol models also provide continuous ethyl-alcohol concentration monitoring for suitable bioethanol and blending processes.

ASTM D1218 – Refractive index / dispersion of hydrocarbon liquids
ASTM D1747 – Refractive index of viscous materials
ASTM D5006 – Fuel-system icing inhibitor in aviation fuels
DR-A1 / DR-A1 Plus digital Abbe refractometers
RX series automatic digital refractometers
Controlled-temperature refractive-index measurement
CM-800α-Ethanol V/V and W/W inline concentration monitoring
CM-ISα-Ethanol intrinsically safe explosion-proof process models

Biodiesel, Bioethanol & Renewable Fuel Testing

CWTC supports both laboratory reference testing and process analysis for B100 biodiesel, FAME blends, fuel ethanol / bioethanol, renewable-diesel feedstocks and biofuel production. ASTM D6751 defines key quality requirements for B100 biodiesel, ASTM D7467 covers B6–B20 biodiesel blends and ASTM D4806 covers denatured fuel ethanol for gasoline blending. Individual quality parameters are measured using the applicable ASTM, EN or other standardized analytical methods.

Metrohm · Biodiesel Reference Analysis

Biodiesel / FAME Laboratory QC

Metrohm titration, Karl Fischer, ion chromatography and oxidation-stability platforms cover important B100 and FAME quality parameters for raw materials, process control and finished biodiesel.

  • ASTM D664 – Acid number by potentiometric titration
  • ASTM D6304 – Water by coulometric Karl Fischer
  • ASTM D7591 – Free & total glycerin by ion chromatography
  • EN 14104 – Acid value in FAME
  • EN 14111 – Iodine number
  • EN 14112 / EN 15751 / EN 16568 – Oxidation stability
Metrohm · Fuel Ethanol / Bioethanol ASTM Analysis

Bioethanol Laboratory Quality Control

Metrohm provides dedicated methods for the chemical quality of denatured fuel ethanol and ethanol-hydrocarbon blends, covering water, acidity, pHe and ionic contaminants relevant to ASTM D4806 fuel-ethanol quality control.

  • ASTM D7923 – Water in ethanol / hydrocarbon blends by Karl Fischer
  • ASTM D7795 – Acidity in ethanol and ethanol blends by titration
  • ASTM D6423 – pHe of denatured fuel ethanol and ethanol blends
  • ASTM D7319 – Chloride & sulfate in fuel ethanol by ion chromatography
  • ASTM D7318 / D7328 – Sulfate-related fuel-ethanol methods
  • IC options for fluoride, acetate, formate, nitrate and sulfate
Metrohm + BÜCHI · Fermentation / Process NIR

Biofuel Process & Fermentation Analysis

NIR provides rapid multi-parameter information during renewable-fuel production. Metrohm NIRS can monitor bioethanol fermentation, while BÜCHI NIR-Online provides continuous process measurements for biodiesel and other suitable production streams.

  • Bioethanol fermentation – ethanol, sugars and Brix
  • Lactic acid, pH and total solids during fermentation
  • BÜCHI biodiesel – acid value, ester content and methanol
  • Monoglyceride, total glycerol and water by BÜCHI NIR-Online
  • Rapid production feedback with reduced laboratory delay
  • NIR used for process QC; specification reference methods remain the reporting basis where required
ATAGO · Continuous Ethanol Concentration

Inline Bioethanol / Ethyl Alcohol Monitoring

ATAGO inline refractometers provide continuous ethyl-alcohol concentration measurement for suitable bioethanol production, blending and transfer processes, giving operators immediate visibility of concentration changes without repeated manual sampling.

  • CM-800α-Ethanol (V/V) – 0.0 to 53.0% ethyl alcohol
  • CM-800α-Ethanol (W/W) – 0.0 to 60.0% ethyl alcohol
  • 4–20 mA / digital output options for process integration
  • Continuous blending and concentration feedback
  • CM-ISα-Ethanol V/V and W/W intrinsically safe explosion-proof models
  • Useful from process adjustment through final concentration checks
Specification note: ASTM D6751, ASTM D7467 and ASTM D4806 are fuel specifications rather than single analytical test procedures. The individual biodiesel and bioethanol parameters are measured using the specific ASTM, EN or other referenced analytical methods shown below. NIR and inline concentration measurement are positioned as rapid process / quality-control tools where appropriate.

Supporting Equipment for Petroleum Laboratories

Petroleum laboratories require more than the primary ASTM analyzer. CWTC can also support sample preparation, laboratory water, glassware, consumables and safe storage of solvents and hazardous materials.

BUCHI Syncore Plus parallel evaporation system

BÜCHI Sample Preparation

Syncore Plus and Rotavapor platforms for parallel concentration, solvent evaporation and general sample-preparation workflows.

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OMNILAB laboratory consumables and equipment

OMNILAB

Laboratory consumables, safety products, accessories and general equipment for routine petroleum laboratory operations.

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IWAKI laboratory glassware

IWAKI Glassware

General and volumetric laboratory glassware for titration, sample preparation, solutions and routine analytical workflows.

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ELGA PURELAB laboratory water system

ELGA LabWater

Purified and ultrapure laboratory water for analytical workflows, reagent preparation and compatible instrument feed requirements.

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asecos safety storage cabinets for flammable solvents

asecos Safety Storage

Fire-resistant and chemical safety cabinets for flammable solvents, acids, alkalis and hazardous materials used in petroleum laboratories.

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ASTM Petroleum Testing – Frequently Asked Questions

Common questions when selecting instruments for ASTM petroleum, fuel and lubricant testing.

Which instrument is used for ASTM D664 Total Acid Number?
ASTM D664 uses potentiometric titration for acid number determination in petroleum products and lubricants. Metrohm automatic titrators can be configured with the appropriate non-aqueous electrode, dosing system and method for TAN analysis.
What is the difference between ASTM D2896 and ASTM D4739 for TBN?
Both methods determine base number by potentiometric titration but use different chemistry and are applied to different lubricant-testing requirements. The correct method should be selected according to the product specification and reporting requirement.
Which Karl Fischer system is used for ASTM D6304?
ASTM D6304 is based on coulometric Karl Fischer titration for water in petroleum products, lubricating oils and additives. Depending on the sample and procedure, direct injection or an oven-based sample introduction technique may be used.
Can Metrohm measure mercaptan sulfur according to ASTM D3227?
Yes. Metrohm provides potentiometric titration methods for mercaptan sulfur and also offers online process-analyzer configurations for mercaptans and hydrogen sulfide in refinery applications.
What is Combustion Ion Chromatography used for in petroleum testing?
Combustion IC converts combustible organic samples into measurable ionic species before ion-chromatographic separation. Petroleum applications include ASTM D7994 for halogens and sulfur in LPG and ASTM D8150 for organic chloride in the naphtha fraction of crude oil.
Can JULABO equipment support ASTM D445 kinematic viscosity testing?
JULABO viscosity baths provide the stable bath temperature required for capillary-viscometer workflows. The DD-31A configuration is suited to petroleum viscosity work where ASTM D445 requires tightly controlled test temperature.
Which ATAGO refractometer methods are relevant to petroleum testing?
ATAGO lists ASTM D1218 for refractive index and refractive dispersion of hydrocarbon liquids, ASTM D1747 for viscous materials and ASTM D5006 for fuel-system icing inhibitor in aviation fuels among the standards supported by its refractometer range.
Can NIR replace ASTM engine methods for RON and MON?
NIR is best positioned as rapid prediction and screening based on calibration models developed against reference laboratory results. Where a specification explicitly requires the primary ASTM reference method, the reference method remains the reporting basis.
Which ASTM methods are important for biodiesel testing?
ASTM D6751 is the specification for B100 biodiesel and ASTM D7467 covers B6–B20 biodiesel blends. Individual laboratory methods include ASTM D664 for acid number, ASTM D6304 for water and ASTM D7591 for free and total glycerin. Oxidation stability and additional FAME parameters may also be controlled using the EN methods referenced by the applicable fuel specification.
Which ASTM methods are relevant to bioethanol / fuel ethanol testing?
ASTM D4806 is a key fuel-ethanol specification. Relevant individual methods include ASTM D7923 for water by Karl Fischer, ASTM D7795 for acidity by titration, ASTM D6423 for pHe and ASTM D7319 for chloride and sulfate by ion chromatography. Metrohm provides analytical platforms and application methods across these measurements.
Can CWTC support bioethanol fermentation and process monitoring?
Yes. Metrohm NIRS can rapidly predict ethanol, sugars, Brix, lactic acid, pH and total solids during fermentation. BÜCHI NIR-Online supports continuous process measurements in suitable biofuel production streams, while ATAGO CM-800α-Ethanol and CM-ISα-Ethanol models provide continuous ethyl-alcohol concentration measurement for suitable process and blending applications.

Need Equipment for Petroleum, Biodiesel, Bioethanol or Renewable-Fuel Testing?

Send CWTC the ASTM / EN method number, fuel type, process stage and expected concentration range. We can identify the appropriate laboratory method, NIR or process analyzer, electrode or accessory, inline concentration monitor, temperature-control requirement and supporting laboratory equipment.

Discuss Your ASTM Requirement